I don't quite understand what you are trying to do, are you trying to widen the field?
If there are more stars after you have inserted the extra extender, the focal length of your optical system should have become shorter, not longer (1450mm) as you have mentioned. Try adjusting your plate solve the other way -- use focal lengths that are shorter than 1250mm.
I don't know about the Maksutov that you are using -- did they specify a back-focus for imaging? If so, adding the extender can cause other problems, like field flatness problem, or even the sensor plate no longer becomes gnomonic tangent planes. The latter will cause star asterisms to change shape and you lose ability to plate solve (especially near the poles).
You can also take an image, save it and upload it to astrometry.net and let it plate solve for you. If astrometry.net cannot match a plate, the star field has sufficient geometric distortion that pretty much no other plate solver could do it. It should give a plate scale in the results window. You then use the plate scale and the sensor's pixel size to compute the focal length of your system.
Try for between 24 and no more than 200 detected stars. Too many stars would just make it more difficult to plate solve (unless the program is set up to reject dimmer stars to being with). The other key to plate solving is to never let the stars saturate. The Max ADU of your plate should not get above 60000.
Clear skies
Chen