1) Is there any need for Dark Frame calibration as the camera has low thermal noise and I shoot with the cooler on at -20C ?
Yes, dark must have same parameters as light.
2) If Dark Frame calibration is not necessary can I ignore Bias correction also ?
Dark frame still useful if you don't take bias.
3) Should I calibrate my Flat Frames (0.005 sec exposure using EL panel at -20C) ? Is there any point calibrating these with a dark frame exposed for 0.005 sec ?
Yes, same temperature.
4) Do I need to change how I calibrate depending on the Gain and Offset settings that i use ?
Gain and offest must be same for calibrate frames, same as light.